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Paper II - INORGANIC CHEMISTRY - I Subject Description : This paper presents an idea about inorganic ring systems and clusters. Some basic concepts of solid state chemistry. Goals : To enable the students to learn some principles and theories in inorganic and solid state chemistry. Objectives : On successful completion of the course the students should have an exposure to the nano technology.Basic idea about the properties of solids Contents

UNIT I

Inorganic rings – chains – cages and clusters – metal clusters – dinuclear, trinuclear, tetra nuclear and hexa - nuclear clusters – organometallic clusters.

UNIT I
I

Borazines – phosphonitrilic compounds – sulpher - nitrogen ring compounds.Metallic state – free electron and band theories – non stochiometry – point defects in solids – Schotty - Frenkel defects – linear and dislocation effects.

UNIT I
II

Electrical properties of solids – superconducting elements – critical temperature – persistent currents – thermoelectric properties – magnetic properties (perfect diamagnetism) – Meissner effect

UNIT I
V

Nuclear chemistry-the nuclues-subatomic particles and their properties –binding energy- N-P ratio in stable and metastable nucluei-different types of nuclear forces-liquid drop model-shell model-mode of radioactive decay

UNIT V
α,β,γ decay-electron capture-nuclear isomerism-internal converstion.Nuclear reactions Q-value, coulombic barrier, cross section, different types of nuclear reactionsprojectiles capture – particle emission, spallation.

Unit VI
Fission fusion-theories of fission, use of fission products, fissile and fertile isotopes – U233, U235, Pu239, Th232, - atomic power projects in India, stellar energy, synthetic elements – application of radio isotopes-hot atom chemistry.

Unit VII
Experimental methods:cloud chamber, nuclear emulsion, bubble chamber, proportional counters-G.M.., scintillation counters. Particle accelerators-cyclotron, synchrotron, betatron., bevatron. Anx.23 D - M Sc Chemistry (SDE) 2007-08 Page 6 of 16

UNIT VIII
Thermal analyses – TG – DTA – principle and instrumentation – Auger electron spectroscopy (AES) – UV photoelectron spectroscopy (UPS/PES) – principles and applications. References : Cotton and Wilkinson : Advanced inorganic Chemistry, Wiley Eastern (P), Ltd., 1968 Gurdeep and Harish : Advanced inorganic Chemistry, Geol Publishing House G.M.Arora : Solid State Chemistry R.A.Alberty and Silbey : Solid State Chemistry J.P.Srivastava : Elements of Solid State Physics Glasstone : Source book of Paper V - INORGANIC CHEMISTRY - II Subject Description : This paper presents an idea about inorganic ring systems and clusters. Some basic concepts of Coordination Chemistry. Goals : To enable the students to learn some principles and theories in inorganic and Coordination Chemistry. Objectives : On successful completion of the course the students should have an exposure to the nano technology.Basic idea about the properties of solids Contents

UNIT I


Methods of preparation of coordination compounds – crystal field theory – spectrochemical series – molecular orbital theory – pi- bonding – magnetic behavior of the transition metal ions.

UNIT I
I


Term symbols for the 3d-block elements and their ions – Orgel diagram – Tanabe- Sugano diagram for Co3+ system – John-Tellar distortions – spin-orbit coupling – Nephelauxetic effect – charge transfer spectra.

UNIT –III
Metal carbonyls – methods of preparation – properties and structure of Iron carbonyls – carbonyl halides – Vasca’s compound – Zeise salt – Structure – hemoglobin – myoglobin - cyanocobalamine – chlorophyll (structure and functions).

UNIT –IV
Substitution reactions in square planar and octahedral complexes – trans effect – redox reactions Homogeneous catalysis by coordination compounds – hydroformylation – carboxylation of methanol – hydrogenation of unsaturated organic compounds.

Unit V
Complexes of molecular nitrogen and oxygen. Nitrosyl complexes, b-diketones, cyanide and isocyanide complexes. Complexes of unsaturated hydrocarbons – alkenes, allyl and dienyls.

UNIT VI
Carbocyclic pi complexes: Cyclopentadienyl and related complexes (synthetic, bonding, structure and reaction). Anx.23 D - M Sc Chemistry (SDE) 2007-08 Page 12 of 16 Arene complexes: Complexes formed by seven and eight membered aromatic rings. Complexes of biochemical importance: Cytochromes, hemoglobin, mycglobin, cyanocobalmine, chlorophyll (structure and functions).

UNIT –VII
Building bridges between inorganic and organic chemistry – fragments – the isolobal analogy – structural implications of the isolobal analogy – the relationship between MLn and MLn-2 fragments - from inorganic to organic chemistry – from organic to inorganic reaction mechanisms – beyond the octahedron.

Unit-VIII
HPLC – principle and application in chemical analyses Diffraction methods – X-ray, electron and neutron diffraction - principle and instrumentation.

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